January 1st, 2018, 07:36 AM  #1 
Newbie Joined: Nov 2017 From: Malaysia Posts: 9 Thanks: 0  slope of a graph
Hi there, I need help! Let's say you have an equation "y=(pq)/(rs)", then you calculate various values of "y" by changing the "p" Screen Shot 20180102 at 0.32.54.png You will plot the ln p versus ln r graph. How can we calculate the slope of the graph by differentiation method? Thank you. Last edited by skipjack; January 2nd, 2018 at 07:21 AM. 
January 1st, 2018, 01:16 PM  #2 
Math Team Joined: Jan 2015 From: Alabama Posts: 3,261 Thanks: 894 
I frankly don't know what you are talking about! You give an equation, $\displaystyle y= \frac{pq}{rs}$, and say "you can calculate various values of 'y' by changing the 'p'". How You still have q, r, and s. What about them? And then you give a chart of, not values of p and y, but values of p and r. "You will plot the ln p versus ln r graph". Okay, now what about y, q, and s? What do they have to do with this? Taking the values of p and r in the chart, (ln p, ln r) would be (0, 2.3026) (0.6931, 2.995) (1.099, 3.401) (1.386, 3.219) (1.609, 2.708) Since the first three pairs. (1, 10), (2, 20), and (3, 30), are r= 10p, the first three numbers on the ln graph are on the straight line ln r= ln p+ ln(10)= ln(p)+ 2.303. But the last three do not fall on that line. Last edited by skipjack; January 2nd, 2018 at 07:18 AM. 
January 1st, 2018, 04:05 PM  #3 
Newbie Joined: Nov 2017 From: Malaysia Posts: 9 Thanks: 0 
Thanks Country Boy The equation that I posted is just an example, not represent anything. We calculate the value of "y" by changing the "p" and "q"; "r";"s" will have fixed value. only "p" will change. The table, my mistake, should have the value for "p" and "y". Then comes the "ln y" versus "ln p" graph. I need to find the slope of this graph (not a straight line) by differentiation method. But what should I differentiate? Thank You 
January 1st, 2018, 06:22 PM  #4 
Math Team Joined: Jan 2015 From: Alabama Posts: 3,261 Thanks: 894 
Okay, so y is a function of p while q, r, and s are constants. Then $y= \left(\frac{q}{rs}\right)p$ is a straight line with slope $\frac{q}{rs}$. However, in order to have y= 10 when p= 1 and y= 20 when p= 2, then $\frac{q}{rs}$ must be equal to 10. On that case, when p= 4, y= 40, not 25, and when p= 5, y= 50, not 50, not 15. What you are saying here is simply not possible. 
January 1st, 2018, 11:04 PM  #5 
Newbie Joined: Nov 2017 From: Malaysia Posts: 9 Thanks: 0 
Thank you Country Boy. What I plot is ln y versus ln p, not the y versus p. I calculated y by using y = pq/rs. Maybe the values are not possible (I got it wrong somewhere), but what I really need to know is that how or what I should differentiate to get the slope for ln y vs ln p. Thank you. Last edited by skipjack; January 2nd, 2018 at 07:24 AM. 
January 2nd, 2018, 04:44 AM  #6 
Math Team Joined: Jan 2015 From: Alabama Posts: 3,261 Thanks: 894 
Since the graph of y vs p is a simple straight line, I have no idea why you would want to graph "ln y vs ln p". If, as you say, $y= \left(\frac{qp}{rs}\right)$ then $\ln(y)= \ln\left(\frac{pq}{rs}\right)= \ln(p)+ \ln(q) \ln(r) \ln(s)$. The "y vs p" graph is a line, through the origin, with slope $\frac{q}{rs}$. The second is a line, not through the origin, with slope 1. Last edited by skipjack; January 2nd, 2018 at 07:15 AM. 
January 2nd, 2018, 07:22 AM  #7 
Senior Member Joined: Oct 2009 Posts: 558 Thanks: 179 
As I understand it, the $y = \frac{pq}{rs}$ is NOT the equation, but just a random example? But do you actually know the right equation? If you don't know the correct equation, the differentiation you desire is not possible.

January 12th, 2018, 07:31 PM  #8 
Newbie Joined: Nov 2017 From: Malaysia Posts: 9 Thanks: 0 
Yes I know the actual equation r = (KcoPcoKo2Po2)/(1+KcoPco+Ko2Po2)^2 It is the Langmuir Isotherm with Kco and Ko2 are the adsorption constant for CO and O2 gas, while Pco and Po2 are the CO and O2 gas partial pressure. I need the derivatives of (d ln r)/(d ln Pco) I start with ln r = ln ((KcoPcoKo2Po2)/(1+KcoPco+Ko2Po2)^2) Thank You 
January 13th, 2018, 03:36 AM  #9  
Math Team Joined: Jan 2015 From: Alabama Posts: 3,261 Thanks: 894  Quote:
$\displaystyle r= \frac{K_{co}P_{co}K_{o_2}P_{o_2}}{(1+ K_{co}P_{co}+ K_{o_2}P_{o2})^2}$ By the properties of logarithms: $\displaystyle ln(r)= ln(K_{co})+ ln(P_{co})+ ln(K_{o_2})_+ ln(P_{o_2}) 2ln(1+ K_{co}P_{co}+ K_{o_2}P_{o_2})$. Now, take the derivative with respect to $\displaystyle ln(P_{co})$. The derivative of function f(x) with respect to function g(x) is, by the chain rule, given by $\displaystyle \frac{df}{dg}\frac{dg}{dx}= \frac{df}{dx}$ so that $\displaystyle \frac{df}{dg}= \frac{\frac{df}{dx}}{\frac{dg}{dx}}$. Here $\displaystyle g(x)= ln(x)$ so that $\displaystyle \frac{dg}{dx}= \frac{1}{x}$ and $\displaystyle \frac{dr}{dg}= \frac{\frac{df}{dx}}{\frac{1}{x}}= x\frac{df}{dx}$. In this problem, "x" is $\displaystyle P_{co}$ so that $\displaystyle \frac{df}{dx}= \frac{d ln(r)}{dP_{co}}= \frac{1}{P_{co}} \frac{2K_{co}}{1+ K_{co}P_{co}+ K_{o_2}P_{o_2}}$. $\displaystyle \frac{d ln(r)}{d ln(P_{co})}$ is $\displaystyle x= P_{co}$ times that: $\displaystyle \frac{d ln(r)}{d ln(P_{co})}= 1 \frac{2K_{co}P_{co}}{1+ K_{co}P_{co}+ K_{o_2}P_{o_2}}$.  
January 13th, 2018, 06:09 AM  #10  
Newbie Joined: Nov 2017 From: Malaysia Posts: 9 Thanks: 0  Quote:
Then if we plot this (d ln r)/(d ln Pco) as "y" exist versus ln Pco ; will it give similar graph with ln r versus ln Pco ??  

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